Collection of lacustrine clays in the Chalco Basin, Mexico for research on sorption and biodegradation of methyl tert-butyl ether (MTBE)

Rosa M. Leal-Bautista and Melissa Lenczewski
Department of Geology and Environmental Geosciences
September 2001


The research grant supported by the Center for Latino and Latin American studies was to evaluate sorption and biodegradation of methyl tert-butyl ether (MTBE) on lacustrine clays from Mexico. MTBE is an additive in gasoline that allows for cleaner burning of fuels to improve air quality. However, the use of MTBE has resulted in contamination of groundwater and is currently the largest ground water contaminant in the USA. In Mexico, MTBE has been blended in the two types of gasoline (Magna-Sin and Premium) and is sold by the state oil company (PEMEX). The aquifer that underlies Mexico D.F. stores a great volume of water, but is strictly restricted due to subsidence that affects this zone. Consequently, other sources of uncontaminated drinking water are needed to supply water in the metropolitan area. One of these alternative sources is the Chalco Basin. The research grant allow us to survey the Chalco Basin (August 13-21) and to collect lacustrine clay samples from the aquitard to determine if this clay will sorb MTBE thus protecting the underlaying aquifer. In addition, it was possible to connect a geological perspective with the social aspects and the problems of public administration that affect this zone.


The fieldwork started at the southeast of the Chalco plain, at an industrial corridor close to the Mexico-Puebla highway. In this location one continuous aquitard core sample was collected from the surface to a depth of 2.5 m. This area has an industrial infrastructure consisting of an electronic plant, a palette construction company, and jeans manufacturing company just to name of few. A sewage canal surrounds the zone with an agua potable pumping station located just 300 m away. Over the last few years the area has also seen bigger domestic settlements within meters of the sewage canals. The presence of many new gas stations and the increase of traffic demonstrate the importance of this study.

 


The second core sample was obtained in the town of Chalco, which is a semi-urban zone where the water supplies, sewage drainage and other public services are scarcely present. The quality of the groundwater is directly related with the quality of life and the well being of the population. In this area, groundwater studies by the government and other institutions have focused on the distribution of water and the number of supply wells but very few have focused the potential for contamination. Since the groundwater level is shallow (around 1.5 m) the potential for contamination can directly affect the inhabitants, especially the children.

 


The third day, we collected two core samples in locations at the central and the edge of the basin at San Miguel Xico and Sta. Cruz Mixquic. In this area, the groundwater quality is influenced by surface agricultural practices and increased population density. The clays in this region were richer in organic matter and were formed under different geological conditions from the two first samples. Gas stations were not located in this area, however, these locations are growing in population and there is a strong presence of transport activities.

 

The Chalco Basin represents different social situations with different ways to obtain water. In the town of Chalco and the industrial corridor, the delivery of water is by trucks (pipas) distributing water to homes that originated from the agua potable pumping station located in the industrial corridor or from local wells. One concern expressed from the local people is that they think that contamination is present in the water. They have detected bad smells, bad colors, and people get sick easily if then they do not boiled the water. Even though the distribution of water is an immense problem for the whole area, the people around the Xico and Mixquic have the opportunity to use artesian wells that makes a positive difference in the quality of their life.


Overall, the fieldwork was successful and will allow for completion of research on sorption of MTBE to clays. Beyond the goal of obtaining samples, it was clear from visiting these areas the importance of environmental geological studies at the Chalco Basin and the necessity to continue with this type of research.